Commit e8851207 authored by Alexander Schoch's avatar Alexander Schoch
Browse files

change title style to sans-serif, update chemifg to chemfig 1.6 (command \charge)

parent c6630519
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......@@ -684,7 +684,7 @@ Das Lewis-Strukturmodell erlaubt uns, chemische Verbindung graphisch darzustelle
\end{subfigure}
\begin{subfigure}[b]{0.33\linewidth}
\centering
\chemfig{H-[:-60]\lewis{46,O}-[0]S(=[2]\lewis{13,O})(=[6]\lewis{57,O})-[0]\lewis{02,O}-[:-60]H}
\chemfig{H-[:-60]\charge{180=\|, -90=\|}{O}-[0]S(=[2]\charge{45=\|,135=\|}{O})(=[6]\charge{-135=\|, -45=|}{O})-[0]\charge{0=\|, 90=\|}{O}-[:-60]H}
\caption{Schwefelsäure}
\label{fig:h2so4}
\end{subfigure}
......@@ -871,7 +871,7 @@ Während für die Bestimmung der Oxidationszahlen beide Bindungselektronen dem \
\begin{minipage}{0.5\linewidth}
\centering
\chemfig{
\lewis{46,O}=[:30]\lewis{2,O}(-[1,0.4,,,,draw=none]\oplus)-[:-30]\lewis{026,O}(-[1,0.4,,,,draw=none]\ominus)
\charge{180=\|, 90=\|}{O}=[:30]\charge{90=\|}{O}(-[1,0.4,,,,draw=none]\oplus)-[:-30]\charge{0=\|, 90=\|, -90=\|}{O}(-[1,0.4,,,,draw=none]\ominus)
}
\end{minipage}
\begin{minipage}{0.49\linewidth}
......@@ -888,7 +888,7 @@ Während für die Bestimmung der Oxidationszahlen beide Bindungselektronen dem \
\begin{minipage}{0.49\linewidth}
\centering
\chemfig{
\lewis{4,O}(-[2,0.4,,,,draw=none]\oplus)~\lewis{0,C}(-[2,0.4,,,,draw=none]\ominus)
\charge{180=\|}{O}(-[2,0.4,,,,draw=none]\oplus)~\charge{0=\|}{C}(-[2,0.4,,,,draw=none]\ominus)
}
\end{minipage}
\end{mdframed}
......@@ -899,7 +899,7 @@ Während für die Bestimmung der Oxidationszahlen beide Bindungselektronen dem \
\begin{minipage}{0.5\linewidth}
\centering
\chemfig{
\chembelow{N}{\oplus}(=[2]\lewis{13,O})(-[:-30]\lewis{26,O}H)(-[:-150]\lewis{246,O}-[6,0.3,,,,draw=none]\ominus)
\chembelow{N}{\oplus}(=[2]\charge{45=\|, 135=\|}{O})(-[:-30]\charge{90=\|, -90=\|}{O}H)(-[:-150]\charge{90=\|, 180=\|, -90=\|}{O}-[6,0.3,,,,draw=none]\ominus)
}
\end{minipage}
\begin{minipage}{0.49\linewidth}
......@@ -921,18 +921,18 @@ Eine Molekülstruktur kann nicht einer bestimmten Grenzstruktur zugeordnet werde
\begin{subfigure}[b]{0.47\linewidth}
\centering
\schemestart
\chemfig{\lewis{46,O}=[:30]\lewis{2,O}(-[1,0.4,,,,draw=none]\oplus)-[:-30]\lewis{026,O}(-[1,0.4,,,,draw=none]\ominus)}
\chemfig{\charge{180=\|, -90=\|}{O}=[:30]\charge{90=\|}{O}(-[1,0.4,,,,draw=none]\oplus)-[:-30]\charge{0=\|, 90=\|, -90=\|}{O}(-[1,0.4,,,,draw=none]\ominus)}
\quad\arrow{<->}\quad
\chemfig{\lewis{06,O}=[:150]\lewis{2,O}(-[3,0.4,,,,draw=none]\oplus)-[:-150]\lewis{426,O}(-[3,0.4,,,,draw=none]\ominus)}
\chemfig{\charge{0=\|, -90=\|}{O}=[:150]\charge{90=\|}{O}(-[3,0.4,,,,draw=none]\oplus)-[:-150]\charge{90=\|, 180=\|, -90=\|}{O}(-[3,0.4,,,,draw=none]\ominus)}
\schemestop
\caption{Grenzstrukturen von Ozon: Durch die Verschiebung der $\pi$-Bindung auf das linke Sauerstoffatom und des nichtbindenden Elektronenpars des formal negativ geladenen Sauerstoffatoms zu einer Doppelbindung kann die andere Grenzstruktur erreicht werden.}
\end{subfigure}\hfill
\begin{subfigure}[b]{0.47\linewidth}
\centering
\schemestart
\chemfig{\chemabove{\lewis{4,O}}{\oplus}~\chemabove{\lewis{0,C}}{\ominus}}
\chemfig{\chemabove{\charge{180=\|}{O}}{\oplus}~\chemabove{\charge{0=\|}{C}}{\ominus}}
\quad\arrow{<->}\quad
\chemfig{\lewis{35,O}=\lewis{0,C}}
\chemfig{\charge{135=\|, -135=\|}{O}=\charge{0=\|}{C}}
\schemestop
\caption{Grenzstrukturen von Kohlenmonoxid: Durch die Verschiebung einer $\pi$-Bindung auf das Sauerstoffatom wird eine weitere Grenzstruktur erreicht werden. Beachte, dass bei C dann die Oktettregel nicht erfüllt wird und diese Resonanozstruktur also eine tiefe Gewichtung besitzt.}
\end{subfigure}
......@@ -947,7 +947,7 @@ Am folgenden Beispiel soll anhand von Chlorsäure (\ce{HClO3}) und Chloriger Sä
\begin{subfigure}[b]{0.5\linewidth}
\centering
\schemestart
\chemfig{\lewis{2,Cl}(=[@{7}:-150]@{8}O)(=[@{5}:-70]@{6}O)(-[@{4}:-30]@{3}\chemabove{O}{\ominus})}
\chemfig{\charge{90=\|}{Cl}(=[@{7}:-150]@{8}O)(=[@{5}:-70]@{6}O)(-[@{4}:-30]@{3}\chemabove{O}{\ominus})}
\schemestop
\chemmove{\draw[shorten <=8pt,shorten >=2pt]
(3).. controls +(90:5mm) and +(60:4mm).. (4);}
......@@ -964,7 +964,7 @@ Am folgenden Beispiel soll anhand von Chlorsäure (\ce{HClO3}) und Chloriger Sä
\begin{subfigure}[b]{0.49\linewidth}
\centering
\schemestart
\chemfig{\lewis{13,Cl}(=[@{7}:-150]@{8}O)(-[@{4}:-30]@{3}\chemabove{O}{\ominus})}
\chemfig{\charge{45=\|, 135=\|}{Cl}(=[@{7}:-150]@{8}O)(-[@{4}:-30]@{3}\chemabove{O}{\ominus})}
\schemestop
\chemmove{\draw[shorten <=8pt,shorten >=2pt]
(3).. controls +(90:5mm) and +(60:4mm).. (4);}
......@@ -1000,21 +1000,21 @@ Lösung: \ref{\ExerciseLabel-Answer}
\begin{mdframed}
\begin{subfigure}[b]{0.33\linewidth}
\centering
\chemfig{\lewis{35,O}=[0]\chemabove{N}{\oplus}(!{ox}{+}{V}{6})=[0]\lewis{17,O}}
\chemfig{\charge{135=\|, -135=\|}{O}=[0]\chemabove{N}{\oplus}(!{ox}{+}{V}{6})=[0]\charge{45=\|, -45=\|}{O}}
\caption{1: \ce{NO2+}}
\end{subfigure}
\begin{subfigure}[b]{0.33\linewidth}
\centering
\schemestart
\chemfig{\lewis{46,O}=[:30]\lewis{2,O}(-[1,0.4,,,,draw=none]\oplus)-[:-30]\lewis{026,O}(-[1,0.4,,,,draw=none]\ominus)}
\chemfig{\charge{180=\|, -90=\|}{O}=[:30]\charge{90=\|}{O}(-[1,0.4,,,,draw=none]\oplus)-[:-30]\charge{0=\|, 90=\|, -90=\|}{O}(-[1,0.4,,,,draw=none]\ominus)}
\arrow{<->}[90,.5]
\chemfig{\lewis{06,O}=[:150]\lewis{2,O}(-[3,0.4,,,,draw=none]\oplus)-[:-150]\lewis{426,O}(-[3,0.4,,,,draw=none]\ominus)}
\chemfig{\charge{0=\|, -90=\|}{O}=[:150]\charge{90=\|, 0=\|}{O}(-[3,0.4,,,,draw=none]\oplus)-[:-150]\charge{90=\|, 180=\|, -90=\|}{O}(-[3,0.4,,,,draw=none]\ominus)}
\schemestop
\caption{2: \ce{O3}}
\end{subfigure}
\begin{subfigure}[b]{0.33\linewidth}
\centering
\chemfig{\lewis{35,O}(!{ox}{-}{II}{6})=[0]C=[0]\lewis{17,O}(!{ox}{-}{II}{6})}
\chemfig{\charge{135=\|, -135=\|}{O}(!{ox}{-}{II}{6})=[0]C=[0]\charge{45=\|, -45=\|}{O}(!{ox}{-}{II}{6})}
\caption{3: \ce{CO2}}
\end{subfigure}
\end{mdframed}
......@@ -1023,25 +1023,25 @@ Lösung: \ref{\ExerciseLabel-Answer}
\begin{mdframed}
\begin{subfigure}[b]{0.33\linewidth}
\centering
\chemfig{B(-[:150]H\lewis{26,O})(-[:30]\lewis{26,O}H)(-[6]\lewis{46,O}H)}
\chemfig{B(-[:150]H\charge{90=\|, -90=\|}{O})(-[:30]\charge{90=\|, -90=\|}{O}H)(-[6]\charge{180=\|, -90=\|}{O}H)}
\caption{4: \ce{B(OH)3}}
\end{subfigure}
\begin{subfigure}[b]{0.33\linewidth}
\centering
\schemestart
\chemfig{Si
(-[::0]\lewis{60,O}-[::60]Si(-[::90,.5,,,dashed])(-[::0,.5,,,dashed])(-[::-90,.5,,,dashed]))
(-[::90]\lewis{20,O}-[::60]Si(-[::90,.5,,,dashed])(-[::0,.5,,,dashed])(-[::-90,.5,,,dashed]))
(-[::180]\lewis{24,O}-[::60]Si(-[::90,.5,,,dashed])(-[::0,.5,,,dashed])(-[::-90,.5,,,dashed]))
(-[::270]\lewis{46,O}-[::60]Si(-[::90,.5,,,dashed])(-[::0,.5,,,dashed])(-[::-90,.5,,,dashed]))
(-[::0]\charge{0=\|, -90=\|}{O}-[::60]Si(-[::90,.5,,,dashed])(-[::0,.5,,,dashed])(-[::-90,.5,,,dashed]))
(-[::90]\charge{90=\|, 0=\|}{O}-[::60]Si(-[::90,.5,,,dashed])(-[::0,.5,,,dashed])(-[::-90,.5,,,dashed]))
(-[::180]\charge{90=\|, 180=\|}{O}-[::60]Si(-[::90,.5,,,dashed])(-[::0,.5,,,dashed])(-[::-90,.5,,,dashed]))
(-[::270]\charge{180=\|, -90=\|}{O}-[::60]Si(-[::90,.5,,,dashed])(-[::0,.5,,,dashed])(-[::-90,.5,,,dashed]))
(!{ox}{+}{IV}{3})
}
\arrow{->}[-90,.5,,,draw=none]
\chemfig{
\vphantom{X}-[@{left,.5}0,.7,,,draw=none]
Si
(-[2]\lewis{42,O}-[:30,.5,,,dashed])
(-[:-30]\lewis{57,O}-[:30,.5,,,dashed])
(-[2]\charge{90=\|, 180=\|}{O}-[:30,.5,,,dashed])
(-[:-30]\charge{-135=\|, -45=\|}{O}-[:30,.5,,,dashed])
(>:[:-165])
(<[:-120])
-[@{right,.5}0,2.5,,,draw=none]\vphantom{X}
......@@ -1052,7 +1052,7 @@ Lösung: \ref{\ExerciseLabel-Answer}
\end{subfigure}
\begin{subfigure}[b]{0.33\linewidth}
\centering
\chemfig{\chemabove{\lewis{35,N}}{\ominus}(!{ox}{-}{II}{6})=[0]C=[0]\chemabove{\lewis{17,N}}{\ominus}(!{ox}{-}{II}{6})}
\chemfig{\chemabove{\charge{135=\|, -135=\|}{N}}{\ominus}(!{ox}{-}{II}{6})=[0]C=[0]\chemabove{\charge{45=\|, -45=\|}{N}}{\ominus}(!{ox}{-}{II}{6})}
\caption{6: \ce{CN2^2-}}
\end{subfigure}
\end{mdframed}
......@@ -1061,21 +1061,21 @@ Lösung: \ref{\ExerciseLabel-Answer}
\begin{mdframed}
\begin{subfigure}[b]{0.33\linewidth}
\centering
\chemfig{\lewis{46,O}=[:30]\lewis{26.,Cl}(!{ox}{+}{IV}{2})=[:-30]\lewis{60,O}}
\chemfig{\charge{180=\|, -90=\|}{O}=[:30]\charge{90=\|, -90=\.}{O}(!{ox}{+}{IV}{2})=[:-30]\charge{0=\|, -90=\|}{O}}
\caption{7: \ce{ClO2}. Radikale sind sehr reaktiv $\rightarrow$ MMS ist Gift!}
\end{subfigure}
\begin{subfigure}[b]{0.33\linewidth}
\centering
\chemfig{\lewis{2,N}(!{ox}{-}{II}{2})(-[:-165]H)(-[:-120]H)-\lewis{2,N}(!{ox}{-}{II}{2})(-[:-15]H)(-[:-60]H)}
\chemfig{\charge{90=\|}{N}(!{ox}{-}{II}{2})(-[:-165]H)(-[:-120]H)-\charge{90=\|}{N}(!{ox}{-}{II}{2})(-[:-15]H)(-[:-60]H)}
\caption{8: \ce{N2H4}\\}
\end{subfigure}
\begin{subfigure}[b]{0.33\linewidth}
\centering
\chemfig{
\lewis{2,P}
(-[:-15]\lewis{62,O}-[::60]H)
(-[:-60]\lewis{46,O}-[::60]H)
(-[:-150]\lewis{06,O}-[::-60]H)
\charge{90=\|}{P}
(-[:-15]\charge{90=\|, -90=\|}{O}-[::60]H)
(-[:-60]\charge{180=\|, -90=\|}{O}-[::60]H)
(-[:-150]\charge{0=\|, -90=\|}{O}-[::-60]H)
}
\caption{9: \ce{P(OH)3}\\}
\end{subfigure}
......
......@@ -34,6 +34,7 @@
\usepackage{multicol} %for quickly setting multicolumn text in a single column document
\usepackage[parfill]{parskip} %no indentation and space between paragraphs
\usepackage{pdfpages} %easily insert pdf pages or whole documents
\usepackage{sectsty}
\usepackage{setspace} %for setting the spacing between lines inside the document
\usepackage{siunitx} %facilitates typesetting SI units + 'S' column type -> aligning numbers e.g. on decimal marker
%\usepackage{subfig} %to place small figures or tables within a single figure
......@@ -103,3 +104,14 @@
\definesubmol{ox}3{-[#3,0.4,,,,draw=none]#2-[4,0.2,,,,draw=none]{#1}}
\setenumerate{label=\arabic*\,)}
% SECTSTY %
\allsectionsfont{\bfseries\sffamily}
% BABEL %
\addto\captionsgerman{
\renewcommand{\contentsname}{
\Large\sffamily % Change font size to whatever you want.
Inhaltsverzeichnis % Change TOC title to whatever you want.
}}
\ No newline at end of file
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